To transfer your music, photos and videos to your new phone, we need to tell KIES where this media is kept. In the left-hand column of KIES, click on either Music,Photos, or Videos and press the button marked Add music folder (or pictures, or video).
Find your Computer's Music, Pictures or Videos folder from the left-hand column of the new window, single-click on it and press the button marked Add folder.
If asked to install a codec, agree. This helps your new phone play any files it may not usually recognise.
Once your music or other media is added to the KIES library, connect your new phone.
Click on your preferred library from the left-hand column, right-click on a track, photo or video and choose transfer to device.
Repeat the process for any other songs, videos or pictures you'd like to have on your Samsung Galaxy S5.